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	<title>The Holographer &#124; Holography &#187; Holograms</title>
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		<title>Free talks on holography</title>
		<link>http://holographer.org/free-talks-on-holography/</link>
		<comments>http://holographer.org/free-talks-on-holography/#comments</comments>
		<pubDate>Wed, 10 Jun 2009 14:16:30 +0000</pubDate>
		<dc:creator>Kaveh</dc:creator>
				<category><![CDATA[Announce]]></category>
		<category><![CDATA[Holography]]></category>
		<category><![CDATA[Holograms]]></category>
		<category><![CDATA[Light Gallery]]></category>
		<category><![CDATA[Linda Law]]></category>
		<category><![CDATA[Rudie Berkhout]]></category>

		<guid isPermaLink="false">http://wordpress.holographer.net/?p=636</guid>
		<description><![CDATA[ Beginning June 13th, each Saturday at 4 pm there will be a gallery talk about Holography at the Play of Light Gallery in Catskill, NY. The list of scheduled talks are as below:  

Saturday June 13th &#8211; The Art of Rudie Berkhout
Saturday June 20th &#8211; Fine Art Holography
Saturday June 27th &#8211; Understanding the [...]]]></description>
			<content:encoded><![CDATA[<p><a href="http://wordpress.holographer.net/wp-content/uploads/2009/06/light-gallery.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2009/06/light-gallery.jpg" alt="Free talks on holography" title="Free talks on holography" width="100" height="100" class="alignleft size-full wp-image-637" /></a> Beginning June 13th, each Saturday at 4 pm there will be a gallery talk about Holography at the Play of Light Gallery in Catskill, NY. The list of scheduled talks are as below: <span id="more-636"></span> </p>
<ul style="list-style: none;">
<li>Saturday June 13th &ndash; <b>The Art of Rudie Berkhout</b></li>
<li>Saturday June 20th &ndash; <b>Fine Art Holography</b></li>
<li>Saturday June 27th &ndash; <b>Understanding the Basic Types of Holograms</b></li>
<li>Saturday July 11th  &ndash; <b>Color in Holograms</b></li>
</ul>
<p>All talks will be from 4&ndash;5&nbsp;pm. Please RSVP to <a href="mailto:playoflight@mhcable.com" target="_blank">playoflight@mhcable.com</a> to reserve a seat. Seating is limited so sign up early&hellip;</p>
<p>			<b>Linda Law</b>, Gallery Director<br />
			460 Main Street, Catskill, NY 12414, 845-510-8081<br />
			<i>As of June 11 the the new gallery number will be 518-203-1972</i>
			</p>
]]></content:encoded>
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		<title>A new panchromatic silver halide emulsion for recording color holograms</title>
		<link>http://holographer.org/a-new-panchromatic-silver-halide-emulsion-for-recording-color-holograms/</link>
		<comments>http://holographer.org/a-new-panchromatic-silver-halide-emulsion-for-recording-color-holograms/#comments</comments>
		<pubDate>Wed, 11 Apr 2007 08:10:34 +0000</pubDate>
		<dc:creator>Kaveh</dc:creator>
				<category><![CDATA[Materials]]></category>
		<category><![CDATA[Article]]></category>
		<category><![CDATA[emulsion]]></category>
		<category><![CDATA[Holograms]]></category>
		<category><![CDATA[Panchromatic]]></category>
		<category><![CDATA[Silver halide]]></category>

		<guid isPermaLink="false">http://wordpress.holographer.net/?p=486</guid>
		<description><![CDATA[
Manuel Ulibarre&#241;am.ulibarrena@umh.es
About the authorManuel received his PhD from the Universidad Miguel Hernandez in Elche, Spain, in 2003. For his project he studied the characteristics of the ultrafine BB640 emulsion in relation to holography. He is currently associate professor of non-destructive testing in the same university. He has been involved in holographic research since 1985, and [...]]]></description>
			<content:encoded><![CDATA[<div class="author-data">
<p><a href="http://wordpress.holographer.net/wp-content/uploads/2009/06/ulibarrena-photo.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2009/06/ulibarrena-photo.jpg" alt="Manuel Ulibarreña" title="Manuel Ulibarreña" width="100" height="121" class="alignleft size-full wp-image-487" /></a><span class="author">Manuel Ulibarre&ntilde;a</span><br /><span><a href="mailto:m.ulibarrena@umh.es">m.ulibarrena@umh.es</a></span></p>
<p class="bio"><strong>About the author</strong><br />Manuel received his PhD from the Universidad Miguel Hernandez in Elche, Spain, in 2003. For his project he studied the characteristics of the ultrafine BB640 emulsion in relation to holography. He is currently associate professor of non-destructive testing in the same university. He has been involved in holographic research since 1985, and his current area of interest remains silver halide holographic recording materials.</p>
</div>
<p><span id="more-486"></span></p>
<div class="download-pdf"><a href="/media/articles/hg00007.pdf" target="_blank">Download PDF</a></div>
<p>All introductory text books about holography make a comparison with photography, saying that photography is a technique that is only capable for recording the intensity of the light scattered by a real object, while holography records both intensity and the phase of that light. What they fail to mention is that when one looks at a display hologram, the image is in most cases monochromatic, so in this case this advantage of holography over photography is completely true only when comparing black and white photography with monochromatic holography.</p>
<p>Today almost all photography is in full color. In order to make the advantage mentioned true for color photography, the holograms must be recorded in full color. This has been obtained in rainbow holography by multiplexing three rainbow holograms with different slit locations, so that an image color is obtained with a single laser and monochromatic recording material. But the color of image depends strongly on the relative position of the slit, and in any case this color is synthesized from three or more monochromatic holograms, with the object illuminated with a monochromatic source. So that although we can get good color, the color cannot be considered as &#x201C;real&#x201D;. True color holograms can only be obtained from the light scattered by an object illuminated by several different wavelengths. Two major practical problems are found when trying to make such a hologram. </p>
<p>The first one is related with the lasers. While red lasers (He&#x2013;Ne or semiconductor lasers) are common in many holographic laboratories (they are cheap and easy to maintain) green and blue lasers are more difficult to find since they are more expensive (e.g.&nbsp;argon ion, frequency-doubled Nd&#x2013;YAG) or have limited holographic performance (e.g.&nbsp;He&#x2013;Cd).
<p> The other problem is the recording material. Traditionally, the materials used for recording color holograms have been panchromatic silver halide emulsions, multiple layer dichromated gelatin and panchromatic photopolymers. For dichromated gelatin, with spectral sensitivity in the blue&#x2013;green zone of the visual spectrum, the red gratings had to be recorded with very special procedures. The blue and the green holograms were recorded individually, not multiplexed, and the final multiple-band hologram had to be built up by laminating the three individual gelatin layers one over the other with complex and costly techniques <span class="cite">[<a  href="#X1">1</a>]</span>. In the late 80&#x2019;s and early 90&#x2019;s, commercial panchromatic photopolymers <span class="cite">[<a  href="#X2">2</a>]</span> emerged as an alternative to DCG <span class="cite">[<a  href="#X3">3</a>]</span>. Silver halide-sensitized gelatin processes with panchromatic emulsion PFG03-C have also been used, with high diffraction efficiencies for single wavelength recordings <span class="cite">[<a  href="#X4">4</a>]</span>. </p>
<p>Silver halide holographic emulsions exhibit a better sensitivity than all the recording materials mentioned above. Nevertheless, although they have been used for recording multiplexed reflection holograms with different laser lines <span class="cite">[<a  href="#X5">5</a>,&nbsp;<a  href="#X6">6</a>]</span>, their usage has been limited by their relatively low index modulation capacity, as well as by their spectral sensitivities, since most of them are sensitized to a single spectral band only. Besides, the material is composed of ultra fine silver halide grains, with an intrinsic absorption band around 400&nbsp;nm. Therefore, blue recordings do not work properly, since they have low diffraction efficiencies due to high levels of absorption and scattering. This led to the use of techniques involving recordings in more than one plate <span class="cite">[<a  href="#X7">7</a>]</span> or more than one recording material <span class="cite">[<a  href="#X8">8</a>]</span>. The use of monochromatic emulsions for multiplexing reflection gratings with different swelling factors between recordings has been also reported <span class="cite">[<a  href="#X9">9</a>]</span>, although in this case we are again working with synthetic color. In all these configurations, emulsions were useful for display and artistic holography. In the mid 90&#x2019;s, new ultra fine grain panchromatic emulsions, especially Slavich PFG-03C, with a mean grain size of 10&nbsp;nm&#x2014;smaller than that of the emulsions previously available&#x2014;boosted advances in these two fields <span class="cite">[<a  href="#X10">10</a>]</span>. More recently, results obtained with a non-commercial ultra fine grain panchromatic emulsion have been reported, with diffraction efficiencies for single exposure diffraction gratings higher than 50% <span class="cite">[<a  href="#X11">11</a>]</span>.
<p> There are several aspects that have to be considered when working with multiplexed reflection holograms with different wavelengths in silver halide materials. The first is the high scattering, mentioned above, that occurs in the blue part of the spectrum. This scattering can be reduced by working with ultra fine grain emulsions. In this study we used the new panchromatic ultra fine grain emulsion BBVPan, based on the existing family of BB emulsions, currently manufactured by Colourholographics Ltd, with a mean grain size of 20&nbsp;nm. The second aspect is related to shrinkage or swelling of the emulsion after the plate is processed, since in reflection holography this is directly related to the wavelength of reconstruction, and this affects the final replay spectrum and color rendition of the grating. The last aspect is the effect of multiple exposures on a single emulsion, since this is associated with a reduction in the diffraction efficiency. This reduction has been historically evaluated as inversely proportional to the square of the total number of recordings <span class="cite">[<a  href="#X12">12</a>]</span>. </p>
<p class="section-head">Experiments</p>
<p>We recorded color reflection holograms using the new panchromatic ultra fine grain emulsion BBVPan, batch no.&nbsp;174. In all our works with BB emulsions we have presensitized them in order to reduce the exposure times. Previous work in reflection holography with BB640 emulsions showed a response in the 604&nbsp;nm range, instead of the expected 633&nbsp;nm of the He&#x2013;Ne laser, an effect caused by the presensitizing bath composed of a 3% triethanolamine (TEA)&#x2013;water solution. TEA is an electron donor that increase the speed of photographic emulsions and photopolymers. But it is also known to be a swelling agent used to reduce the replay wavelength of the holograms, and has this additional effect when used in presensitization. We found that an additional water bath following the first TEA solution bath reduces the swelling effect. The soaking time in this second bath is important and has to be adjusted to obtain the proper wavelength at reconstruction. </p>
<p>In all the tests reported here, plates were presensitized by soaking for 2&nbsp;min in a 3% TEA water solution, 7&nbsp;min in a deionized water bath, drying with a photographic roll and warm air, and leaving in the exposure room for half an hour in normal laboratory conditions (20<sup >&#x2218;</sup> and 60% RH) <span class="cite">[<a  href="#X13">13</a>]</span>.
<p> For the above characterization study, plates were exposed to single collimated beams in a Denisyuk configuration <span class="cite">[<a  href="#X14">14</a>]</span> using a blue He&#x2013;Cd laser (wavelength 442&nbsp;nm), a green frequency-doubled Nd&#x2013;YAG laser (wavelength 532&nbsp;nm), and a red He&#x2013;Ne laser (wavelength 632.8&nbsp;nm). The recording setup consists of an optical sandwich composed of a first surface mirror that reflects the incident beam back into the emulsion. The emulsion side of the plate is in contact with the mirror via an index matching fluid, and the glass side is in contact with an anti-reflection coated glass plate via another thin layer of index matching fluid to prevent internal reflections. The setup schematic is shown in <a  href="#x1-20011">figure&nbsp;1<!--tex4ht:ref: setup1 --></a>. </p>
<p><a name="x1-20011"></a><div id="attachment_490" class="wp-caption aligncenter" style="width: 389px"><a href="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr001.jpg"><img src="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr001.jpg" alt="Figure 1: Recording setup used for the characterization study of the BBPan emulsions." title="Figure 1: Recording setup used for the characterization study of the BBPan emulsions." width="379" height="416" class="size-full wp-image-490" /></a><p class="wp-caption-text">Figure 1: Recording setup used for the characterization study of the BBPan emulsions.</p></div></p>
<p>With this configuration spatial frequencies of 7145&nbsp;l/mm (blue), 5936&nbsp;l/mm (green) and 4990&nbsp;l/mm (red) were recorded (considering a refractive index of 1.579 for the unexposed emulsion). The sandwich was mounted on a computer controlled motorized holder which enabled us to record 9 gratings with different exposure energies on a 2&#x201D; &#x00D7; 2.5&#x201D; plate. The size of the plate was obtained by cutting each of the 4&#x201D; &#x00D7; 5&#x201D; plate into 4 pieces, since at the time we performed our study we had only 5 of these plates available. </p>
<p>The diffuse object color hologram study was performed with a holographic setup in a Denisyuk configuration shown in <a  href="#x1-20022">figure&nbsp;2<!--tex4ht:ref: setup2 --></a>. The folding mirrors were sequentially placed in order to multiplex the three holograms, starting with the blue, then the green and finally the red laser. Plate size for this study was 2&#x201D; &#x00D7; 2.5&#x201D;, except for the last one that was 4&#x201D; &#x00D7; 2.5&#x201D;. </p>
<p><a name="x1-20022"></a><div id="attachment_496" class="wp-caption aligncenter" style="width: 435px"><a href="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr002.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr02.png" alt="Figure&nbsp;2: Recording setup used for the diffuse object color hologram study of the BBPan emulsions." title="Figure&nbsp;2: Recording setup used for the diffuse object color hologram study of the BBPan emulsions." width="425" height="284" class="size-full wp-image-496" /></a><p class="wp-caption-text">Figure&nbsp;2: Recording setup used for the diffuse object color hologram study of the BBPan emulsions.</p></div></p>
<p>Exposed plates were developed with AAC developer (Ascorbic Acid 18&nbsp;g/l + Sodium Carbonate 60&nbsp;g/l) <span class="cite">[<a  href="#X15">15</a>]</span>. After washing they were bleached with fixation-free rehalogenating bleach R-10 (Potassium Dichromate 2&nbsp;g/l + Sulphuric Acid 10&nbsp;cc/l + Potassium Bromide 35&nbsp;g/l). After bleaching, the plates were washed and soaked in deionized water with a few drops of Photoflo and Acetic Acid to prevent printout, and dried in the normal laboratory conditions mentioned above. </p>
<p>After drying, the plates recorded in both the characterization setup and the diffuse object setup were analysed using a fibre fed spectroradiometer. With this device we measured the zero order of the grating with a replay angle of 0<sup >&#x2218;</sup>, matching the recording geometry. A short arc xenon lamp was used as the light source, collimated and polarized perpendicular to the plane of incidence to match the recording conditions. Light was collected by an optical fibre that fed the spectrophotometer and data were transferred to a computer for storage and analysis. Reflection losses were experimentally evaluated and found to have a value of 6.7%. The schematic of this setup is shown in <a  href="#x1-20033">figure&nbsp;3<!--tex4ht:ref: setup3 --></a>. </p>
<p><a name="x1-20033"></a><div id="attachment_500" class="wp-caption aligncenter" style="width: 471px"><a href="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr003.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr03.png" alt="Figure&nbsp;3: Analysis setup." title="Figure&nbsp;3: Analysis setup." width="461" height="351" class="size-full wp-image-500" /></a><p class="wp-caption-text">Figure&nbsp;3: Analysis setup.</p></div></p>
<p>Two different studies were performed: a preliminary spectral sensitivity characterization of the plates, followed by a study of multiplexed gratings on a single plate with plane gratings and a diffusing object. </p>
<p class="section-head">Characterization of the Plates</p>
<p>The plates were first tested for single wavelength recordings with each of the laser beams used in order to check their spectral sensitivity and the response of the material when recording holographic reflection gratings. Three sets of tests, one for each wavelength, were carried out, including presensitizing, exposing, processing and analysis as explained above. Exposure energies ranged from 30 to 2400&nbsp;J/cm<sup >2</sup> for the He&#x2013;Cd laser and from 150 to 2400&nbsp;J/cm<sup >2</sup> for the frequency-doubled Nd&#x2013;YAG and He&#x2013;Ne lasers. </p>
<p class="section-head">Multiplexed Holograms</p>
<p>In this case, the exposure of the reflection gratings was made sequentially on the same area of the plate, starting with the blue wavelength, followed by green and then red. We obtained a set of multiplexed reflection gratings with different exposure energy combinations for each wavelength, ranging from 120 to 225&nbsp;J/cm<sup >2</sup> for the He&#x2013;Cd laser, 150 to 250&nbsp;J/cm<sup >2</sup> for the frequency-doubled Nd&#x2013;YAG laser and 800 to 1200&nbsp;J/cm<sup >2</sup> for the He&#x2013;Ne laser. </p>
<p class="section-head">Results</p>
<p>Single sensitivities of BBVPan plates for each of the three recording wavelengths are presented in <a  href="#x1-50014">figure&nbsp;4<!--tex4ht:ref: single --></a>, and the most relevant results are summarized in <a  href="#x1-50031">table&nbsp;1<!--tex4ht:ref: tablesingle --></a>. From these results it is clear that the exposure energy for maximum Diffraction Efficiency (DE) of this emulsion is the highest for the blue wavelength ( 320&nbsp;J/cm<sup >2</sup>), followed by the green (1200&nbsp;J/cm<sup >2</sup>) and with the lowest sensitivity for the red (2400&nbsp;J/cm<sup >2</sup>). Replay wavelengths match very closely with those used at recording, with an error of less than 2%. This wavelength shift can be modified by changing the soaking bath times in the presensitizing process. </p>
<p><a name="x1-50014"></a><div id="attachment_502" class="wp-caption aligncenter" style="width: 314px"><a href="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr004.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr004.jpg" alt="Figure&nbsp;4: Dependence  of  the  diffraction  efficiency  of  BBVPan  plates  on exposure energy for each of the recording wavelengths." title="Figure&nbsp;4: Dependence  of  the  diffraction  efficiency  of  BBVPan  plates  on exposure energy for each of the recording wavelengths." width="304" height="457" class="size-full wp-image-502" /></a><p class="wp-caption-text">Figure&nbsp;4: Dependence  of  the  diffraction  efficiency  of  BBVPan  plates  on exposure energy for each of the recording wavelengths.</p></div></p>
<p><a name="x1-50025"></a><div id="attachment_503" class="wp-caption aligncenter" style="width: 313px"><a href="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr005.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr005.jpg" alt="Figure&nbsp;5: Transmission spectra corresponding to the three single wavelength holographic reflection gratings with maximum DE recorded on three BBVPan plates." title="Figure&nbsp;5: Transmission spectra corresponding to the three single wavelength holographic reflection gratings with maximum DE recorded on three BBVPan plates." width="303" height="461" class="size-full wp-image-503" /></a><p class="wp-caption-text">Figure&nbsp;5: Transmission spectra corresponding to the three single wavelength holographic reflection gratings with maximum DE recorded on three BBVPan plates.</p></div></p>
<div class="float">
<table class="float"style="border-top: 1px dotted #6464dc; padding-top: 2px; line-height: 2em;">
<tr class="float">
<td class="float"> Table&nbsp;1.&nbsp;Relevant  results  obtained  for  single-wavelength  recording  of  holographic  reflection gratings on BBVPan plates <a name="x1-50031"></a>
<div class="centerline"><!--tex4ht:inline-->
<div class="tabular">
<table class="tabular" cellspacing="2" cellpadding="5" frame="void" id="TBL-1-" width="100%" style="border-bottom: 1px dotted #6464dc; padding-bottom: 2px; ">
<colgroup id="TBL-1-1g">
<col  id="TBL-1-1" />
<col  id="TBL-1-2" />
<col  id="TBL-1-3" />
<col  id="TBL-1-4" />
<col  id="TBL-1-5" /></colgroup>
<tr    bgcolor="#ecec9c"   valign="baseline" id="TBL-1-1-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-1-1"   class="td11">  Recording  </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-1-2"   class="td11">  Max DE (%)  </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-1-3"   class="td11">  Energy for max.  </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-1-4"   class="td11">  Replay  (nm)  </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-1-5"   class="td11">  &#x0394; (nm)  </td>
</tr>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-1-2-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-2-1"   class="td11">   (nm)      </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-2-2"   class="td11">                    </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-2-3"   class="td11">   DE (J/cm<sup >2</sup>)   </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-2-4"   class="td11">                       </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-2-5"   class="td11">                </td>
</tr>
<tr    bgcolor="#ecec9c"   valign="baseline" id="TBL-1-3-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-3-1"   class="td11">  442          </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-3-2"   class="td11">        73.7        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-3-3"   class="td11">           320         </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-3-4"   class="td11">        448.6        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-3-5"   class="td11">     25.2     </td>
</tr>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-1-4-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-4-1"   class="td11">  532           </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-4-2"   class="td11">        82.8        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-4-3"   class="td11">         1200         </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-4-4"   class="td11">        536.7        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-4-5"   class="td11">     29.0     </td>
</tr>
<tr    bgcolor="#ecec9c"   valign="baseline" id="TBL-1-5-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-5-1"   class="td11">  632.8        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-5-2"   class="td11">        74.1        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-5-3"   class="td11">         2400         </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-5-4"   class="td11">        645.9        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-1-5-5"   class="td11">     26.0     </td>
</tr>
</table>
</div>
</div</td>
</tr>
</table>
</div>
<p>One of the key characteristics of this new material is its even response to all the wavelengths we used. Former western emulsions suffered from high absorption in the blue region of the spectrum. This limited their use for recording multiplexed color reflection holograms on a single plate. With the experimental setup described above, we worked not only with three well-separated wavelengths, but with the highest spatial frequencies holographically achievable in each case. The results obtained show that the maximum diffraction efficiency with each of these spatial frequencies is almost constant, with a small drop in the case of the blue wavelength due to the proximity of the absorption band of the silver halide grains, located at about 400&nbsp;nm, and the absorption band of the supporting glass plate and the gelatin emulsion. For the red wavelength there is another small drop in diffraction efficiency, but this time due only to the low sensitivity of the plate in this region of the spectrum. Nevertheless, all maximum DE values for single wavelength are well above 70%. </p>
<p>The transmission spectra of the recordings corresponding to the three diffraction efficiency maxima are shown in <a  href="#x1-50025">figure&nbsp;5<!--tex4ht:ref: 3single --></a>. The blue band is affected by the absorption of the ultra fine grain emulsion referred to above, thus reducing the diffraction efficiency of this recording, although the zero order is of the same magnitude as that obtained with the green wavelength.
<p> With all the information obtained after this preliminary study, we multiplexed three reflection gratings, each with a different wavelength, onto a single plate, following the procedure described in section&nbsp;<a  href="#x1-20002">2<!--tex4ht:ref: exp --></a>. The best result was obtained with a sequence of exposures with energies of 150 (442&nbsp;nm) + 250&nbsp;(532&nbsp;nm) + 1200 (632.8&nbsp;nm) J/cm<sup >2</sup>, at which the diffraction efficiencies of each band are balanced, as shown in <a  href="#x1-50042">table&nbsp;2<!--tex4ht:ref: table3 --></a>, with the corresponding spectral transmission curve shown in <a href="#x1-50056">figure&nbsp;6<!--tex4ht:ref: 3fit --></a>. The DE for all the recordings is higher than 52%, which indicates a high index modulation capacity for this material. Other exposure energy sets were tested, and small changes in one of the exposures were seen to substantially affect the DE of all three bands.</p>
<div class="float"  >
<table class="float" style="border-top: 1px dotted #6464dc; border-bottom: 1px dotted #6464dc; padding-top: 2px; padding-bottom: 2px; ">
<tr class="float">
<td class="float"  >                                                                                                                                        Table&nbsp;2.&nbsp;Relevant results obtained for multiplexed holographic reflection gratings recorded with three wavelengths on BBVPan plates<a    id="x1-50042"></a>
<div   class="centerline"><!--tex4ht:inline--></p>
<div class="tabular">
<table class="tabular"  cellspacing="2" cellpadding="5" frame="void" id="TBL-2-" width="100%">
<colgroup id="TBL-2-1g">
<col  id="TBL-2-1" />
<col  id="TBL-2-2" />
<col  id="TBL-2-3" />
<col  id="TBL-2-4" />
<col  id="TBL-2-5" /></colgroup>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-2-1-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-2-1-1"   class="td11">  Recording  </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-1-2"   class="td11">   Exposure   </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-1-3"   class="td11">  DE (%)  </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-1-4"   class="td11">  Replay  (nm)  </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-1-5"   class="td11">  &#x0394; (nm)  </td>
</tr>
<tr    bgcolor="#ecec9c"   valign="baseline" id="TBL-2-2-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-2-2-1"   class="td11">   (nm)    </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-2-2"   class="td11">  (J/cm<sup >2</sup>)  </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-2-3"   class="td11">              </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-2-4"   class="td11">                       </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-2-5"   class="td11">                </td>
</tr>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-2-3-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-2-3-1"   class="td11">  442          </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-3-2"   class="td11">      150      </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-3-3"   class="td11">    57.1    </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-3-4"   class="td11">        452.5        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-3-5"   class="td11">     19.4     </td>
</tr>
<tr    bgcolor="#ecec9c"   valign="baseline" id="TBL-2-4-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-2-4-1"   class="td11">  532         </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-4-2"   class="td11">      250      </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-4-3"   class="td11">    62.1    </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-4-4"   class="td11">        546.3        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-4-5"   class="td11">     17.2     </td>
</tr>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-2-5-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-2-5-1"   class="td11">  632.8        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-5-2"   class="td11">      1200      </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-5-3"   class="td11">    52.6    </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-5-4"   class="td11">        650.8        </td>
<td valign="middle"  align="center" style="white-space:nowrap;" id="TBL-2-5-5"   class="td11">     19.4     </td>
</tr>
</table></div>
</div>
</td>
</tr>
</table>
</div>
<p>In order to check that the effect of crosstalk between diffraction bands was negligible, we applied a model based on Kogelnik&#x2019;s theory with three bands <span class="cite">[<a  href="#X16">16</a>]</span>. With this model we obtained the index modulation and effective thickness of the multiple band recordings with great accuracy. Experimental data were fitted and a good match was obtained, as can be seen in <a  href="#x1-50056">figure&nbsp;6<!--tex4ht:ref: 3fit --></a>, in which the dashed curve corresponds to the theoretical approach. The best result was obtained for an effective thickness d of 7.3&nbsp;m. Approaches with three different values of the index modulation n<sub >1</sub>, one for each wavelength, were tried, but the best result was obtained when each one had the same value, namely 0.027. </p>
<p><a name="x1-50056"></a><div id="attachment_507" class="wp-caption aligncenter" style="width: 313px"><a href="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr006.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr006.jpg" alt="Figure&nbsp;6: Transmission  spectrum  of  the  multiplexed  holographic  reflection grating recorded on a single BBVPan plate. The dashed line shows the result obtained with the theoretical simulation." title="Figure&nbsp;6: Transmission  spectrum  of  the  multiplexed  holographic  reflection grating recorded on a single BBVPan plate. The dashed line shows the result obtained with the theoretical simulation." width="303" height="453" class="size-full wp-image-507" /></a><p class="wp-caption-text">Figure&nbsp;6: Transmission  spectrum  of  the  multiplexed  holographic  reflection grating recorded on a single BBVPan plate. The dashed line shows the result obtained with the theoretical simulation.</p></div></p>
<p>After looking at the results obtained in this study with reflection diffraction gratings, several of the points raised in the introduction may now be discussed. The high diffraction efficiencies obtained with the multiplexed holograms contradicts what has been said about a reduction in diffraction efficiency of multiplexed holograms (although those studies were done with angular multiplexing). In fact, results obtained with this material show that its modulation capacity is greater than that needed to record a unique holographic grating, since if we consider such a case, we can obtain a maximum index modulation of 0.054, while if we use the sum of the three individual index modulations as the storage capacity of the material, a value of 0.081 is obtained. This is much higher than any other reported value for a silver halide emulsion. Therefore, the total DE is not reduced by multiplexing several gratings, but is increased to another value that corresponds to the real storage capacity of this emulsion. </p>
<p>After completing this study with gratings, and considering the sensitivity values obtained, we continued with a study with diffuse object holograms. We chose an object containing tones which were hard to reproduce, such as skin color, yellow-orange, and blue. The best result, one with high brightness and good color reproduction, was obtained with exposure energies of: 225&nbsp;J/cm<sup >2</sup> (He&#x2013;Cd), 350&nbsp;J/cm<sup >2</sup> (Nd:YAG) and 1.5&nbsp;mJ/cm<sup >2</sup> (He&#x2013;Ne), values which are not very far form the optimal values obtained for diffraction gratings. A color reproduction of the final hologram, replayed with an halogen lamp, and with the real object under the same illumination, is shown in <a  href="#x1-50067">figure&nbsp;7<!--tex4ht:ref: juanito --></a>. </p>
<p><a name="x1-50067"></a><div id="attachment_508" class="wp-caption aligncenter" style="width: 466px"><a href="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr007.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr007.jpg" alt="Figure&nbsp;7: Color reproduction of the final diffuse object hologram compared with the real object under the same reconstruction/illumination source." title="Figure&nbsp;7: Color reproduction of the final diffuse object hologram compared with the real object under the same reconstruction/illumination source." width="456" height="301" class="size-full wp-image-508" /></a><p class="wp-caption-text">Figure&nbsp;7: Color reproduction of the final diffuse object hologram compared with the real object under the same reconstruction/illumination source.</p></div></p>
<p>Replay wavelengths with an angle of reconstruction of 45<sup >&#x2218;</sup> are 445&nbsp;nm, 538&nbsp;nm and 639&nbsp;nm, which are very close to the recording wavelengths. A sample of the transmittance spectrum obtained with the analysis device with the probe beam incident at an arbitrary location of the hologram is shown in figure&nbsp;<a  href="#x1-50078">8<!--tex4ht:ref: juanito_spectrum --></a>. Estimated diffraction efficiencies for each of the bands are around 20% for the blue and green bands and around 40% for the red, which are not bad values for a diffuse object. It must be noted that the transmittance spectrum depends on the area of the hologram sampled. </p>
<p><a name="x1-50078"></a><div id="attachment_509" class="wp-caption aligncenter" style="width: 315px"><a href="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr008.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2007/04/hgr008.jpg" alt="Figure&nbsp;8: Transmission spectrum of the diffuse object hologram recorded on a single BBVPan plate." title="Figure&nbsp;8: Transmission spectrum of the diffuse object hologram recorded on a single BBVPan plate." width="305" height="456" class="size-full wp-image-509" /></a><p class="wp-caption-text">Figure&nbsp;8: Transmission spectrum of the diffuse object hologram recorded on a single BBVPan plate.</p></div></p>
<p class="section-head">Conclusions</p>
<p>We tested the new BBVPan panchromatic holographic emulsions for reflection holography. The material was first evaluated using single recordings with three different wavelengths, and a DE higher than 72% was reached in all cases. After characterization, the plates were used to record a three-band holographic reflection grating with spatial frequencies from 5000&nbsp;l/mm to more than 7000&nbsp;l/mm, all with high diffraction efficiencies, namely over 52% for each of the three bands. The study with diffuse objects rendered good color images with good diffraction efficiencies. With the properties mentioned, this material can be used to manufacture holographic combiners for projection display systems, as well as for color display holograms. </p>
<p class="section-head">Acknowledgements</p>
<p>I am grateful Michael Medora of Colourholographics Ltd&nbsp;for providing the holographic plates used in this work.</p>
<p class="section-head">References</p>
<p class="bibitem"><span class="biblabel">   [1]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X1"></a>         &nbsp;&nbsp;J. R. Magari&ntilde;os and D. J. Coleman&nbsp;1985 Holographic mirrors <i>Opt.     Eng.</i> 24 (5) 769&#x2013;780     </p>
<p class="bibitem"><span class="biblabel">   [2]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X2"></a>        &nbsp;&nbsp;T. H. Jeong and E. Wesley&nbsp;1989 True color holography on du Pont     photopolymer material <i>Holosphere</i> 16 (4) 20     </p>
<p class="bibitem"><span class="biblabel">   [3]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X3"></a>          &nbsp;&nbsp;T. J. Trout, W. J. Gambogi and S. H. Stevenson&nbsp;1995     Photopolymer materials for color holography Proc. Int. Conf. on Applications of Optical Holography SPIE 94&#x2013;105     </p>
<p class="bibitem"><span class="biblabel">   [4]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X4"></a>         &nbsp;&nbsp;J. M. Kim, B. S. Choi, Y. S. Choi, J. M. Kim, H. I. Bjelkhagen and     N. J. Phillips&nbsp;2002 Holographic optical elements recorded in silver halide     sensitized gelatin emulsions. part ii. Reflection holographic optical elements     <i>Appl. Opt.</i> 41 (8) 1522&#x2013;1533     </p>
<p class="bibitem"><span class="biblabel">   [5]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X5"></a>         &nbsp;&nbsp;L. H. Lin, K. S. Pennington, G. W. Stroke and A. E. Labeyrie&nbsp;1966     Multicolor holographic image reconstruction with white-light &nbsp;illumination <i>Bell     Syst. Tech. J.</i> 45 659&#x2013;661     </p>
<p class="bibitem"><span class="biblabel">   [6]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X6"></a>          &nbsp;&nbsp;J. Upatnieks, J. Marks and R. Fedorowicz&nbsp;1966 Color     holograms for white light reconstruction <i>Appl. Phys. Lett.</i> 8 (11) 286&#x2013;287     </p>
<p class="bibitem"><span class="biblabel">   [7]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X7"></a>         &nbsp;&nbsp;P. Hariharan, W. H. Steel and Z. S. Hegedus&nbsp;1977 Multicolor     holographic imaging with a white-light source <i>Opt. Lett.</i> 1 8&#x2013;9     </p>
<p class="bibitem"><span class="biblabel">   [8]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X8"></a>         &nbsp;&nbsp;T. Kubota&nbsp;1986 Recording of high quality color holograms <i>Appl.     Opt.</i> 25 4141&#x2013;4145     </p>
<p class="bibitem"><span class="biblabel">   [9]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X9"></a>               &nbsp;&nbsp;P. M. Pombo, R. M. Oliveira and Jo an L. Pinto&nbsp;2002 Color     control in reflection holograms recorded in Slavich PFG-01 emulsions Practical     Holography XVI and Holographic Materials VIII ed T.&nbsp;John Trout&nbsp;&nbsp; and SPIE     399&#x2013;404</p>
<p class="bibitem"><span class="biblabel">  [10]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X10"></a>         &nbsp;&nbsp;H. I. Bjelkhagen, T. H. Jeong and D. Vukicevic&nbsp;1996 Color     reflection holograms recorded in a panchromatic &nbsp;ultrahigh-resolution     single-layer silver halide emulsion <i>J. Imaging Sci. Technol.</i> 40 (2) 134&#x2013;146     </p>
<p class="bibitem"><span class="biblabel">  [11]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X11"></a>           &nbsp;&nbsp;C. Wang, D. Pu, T. Zhu, J. Wu and M. Tang&nbsp;2002 Panchromatic     ultra-fine-grain silver halide emulsions and their &nbsp;properties in reflection     holography Holography, Diffractive Optics and Applications ed&nbsp;Y. Sheng, D. Hsu     and J. Chen&nbsp;&nbsp; SPIE 121&#x2013;125     </p>
<p class="bibitem"><span class="biblabel">  [12]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X12"></a>          M.&nbsp;K.&nbsp;Shevtsov&nbsp;1985 Diffraction efficiency of phase holograms for     exposure superposition <i>Sov. J. Opt. Technol.</i> 52 1&#x2013;3     </p>
<p class="bibitem"><span class="biblabel">  [13]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X13"></a>       M.&nbsp;&nbsp;Medora&nbsp;2003 Colourholographics Ltd, Braxted Park, Gt.     Braxted, Witham, Essex, &nbsp;CM8 3XB England (Personal communication)     </p>
<p class="bibitem"><span class="biblabel">  [14]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X14"></a>         Y.&nbsp;N.&nbsp;Denisyuk&nbsp;2001 Photographic Reconstruction of the Optical     Properties of an Object in its Own Scattered Radiation Field, volume MS 171 of     Milestone Series SPIE 22&#x2013;24     </p>
<p class="bibitem"><span class="biblabel">  [15]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X15"></a>         &nbsp;&nbsp;M. Ulibarrena, M. J. M&eacute;ndez, L. Carretero, R. Madrigal and     A. Fimia&nbsp;July 2002 Comparison of direct, rehalogenating and solvent     bleaching processes with BB640 plates <i>Appl. Opt.</i> 41 (20) 4120&#x2013;4123     </p>
<p class="bibitem"><span class="biblabel">  [16]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X16"></a>         &nbsp;&nbsp;M. Ulibarrena, L. Carretero, R. F. Madrigal, S. Blaya and A.     Fimia&nbsp;2003 Multiple band holographic reflection gratings recorded in new     ultra-fine grain emulsion BBVPan <i>Opt. Express</i> 11 (25) 3385&#x2013;3392 </p>
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		<title>Smart holograms</title>
		<link>http://holographer.org/smart-holograms/</link>
		<comments>http://holographer.org/smart-holograms/#comments</comments>
		<pubDate>Sun, 11 Apr 2004 19:06:59 +0000</pubDate>
		<dc:creator>Kaveh</dc:creator>
				<category><![CDATA[Materials]]></category>
		<category><![CDATA[Article]]></category>
		<category><![CDATA[Holograms]]></category>
		<category><![CDATA[Jeff Blyth]]></category>

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		<description><![CDATA[
Jeff Blythjeff@biotech.cam.ac.uk
About the authorAfter graduating in 1973 in Applied Chemistry he worked in a company with dichromated gelatin, unrelated to holography. In &#x2019;77, he was amazed to see a holographic pendant made using the very material he was researching. His life &#x2018;changed for ever&#x2019;. He subsequently worked on photopolymer materials for Ilford, which became the [...]]]></description>
			<content:encoded><![CDATA[<div class="author-data">
<p><a href="http://wordpress.holographer.net/wp-content/uploads/2009/06/blyth-photo1.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2009/06/blyth-photo1.jpg" alt="blyth-photo1" title="blyth-photo1" width="100" height="121" class="alignleft size-full wp-image-472" /></a><span class="author">Jeff Blyth</span><br /><span><a href="mailto:jeff@biotech.cam.ac.uk">jeff@biotech.cam.ac.uk</a></span></p>
<p class="bio"><strong>About the author</strong><br />After graduating in 1973 in Applied Chemistry he worked in a company with dichromated gelatin, unrelated to holography. In &#x2019;77, he was amazed to see a holographic pendant made using the very material he was researching. His life &#x2018;changed for ever&#x2019;. He subsequently worked on photopolymer materials for Ilford, which became the subject for an MPhil at Wolverhampton Polytechnic. Since &#x2019;91 he has been involved in &#x2018;blue sky&#x2019; research at the Institute of Biotechnology in Cambridge, UK. Jeff is the recipient of the Royal Photographic Society&#x2019;s Saxby award for 2003 <br />(<a href="http://www.holography.co.uk/events/saxbyaward/jeffblyth/jeff.htm" target="_blank">http://www.holography.co.uk/events/saxbyaward/jeffblyth/jeff.htm</a>).</p>
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<div class="download-pdf"><a href="/media/articles/hg00002.pdf" target="_blank">Download PDF</a></div>
<p>It is always impressive to see how a green reflection hologram temporarily changes to red when you let breath-moisture condense on the gelatin surface. (This effect is due to the gelatin swelling and the inter-fringe distance in the gelatin film increasing so that it reflects red instead of green light.) Apart from the obvious use of this effect in measuring the relative humidity of gases or liquids&nbsp;<span class="cite">[<a  href="#X1">1</a>]</span> our team at the Institute of Biotechnology wanted to use this effect to make many other types of measurements.</p>
<p>It was at the end of August 1995 that I tried an experiment which was to cause a revolution in our Institute and beyond! For over three years I had been experimenting on making so called &#x201C;Lippmann&#x201D; silver halide emulsions using basically the traditional method of squirting, alternately, solutions of silver nitrate and potassium bromide into a hot solution of gelatin&nbsp;<span class="cite">[<a  href="#X2">2</a>]</span>. The precipitated grains of silver bromide (AgBr) are very much finer in Lippmann emulsions than in emulsions used for normal photography. To be able to record holographic fringes satisfactorily the photosensitive grains need to have diameters at least a factor of 10 smaller than the width of a hologram fringe (around 200&nbsp;nm, i.e.&nbsp;half the laser wavelength divided by the refractive index of the gelatin layer.) Conventional fine-grained photographic emulsions have grain sizes around 1000&nbsp;nm or more. The experiment which changed everything for us was to take a just a <b>precoated</b> and hardened gelatin layer and to try and produce those vitally small AgBr grains inside the layer just by using a silver ion diffusion process, while still achieving a sufficient degree of photosensitivity&nbsp;<span class="cite">[<a  href="#X3">3</a>]</span>. The moment of success came when I glimpsed a holographic image on a coated microscope slide of a polished penny.&#x2014;One of those all-too-rare eureka moments! </p>
<p><a name="x1-10011"></a><div id="attachment_475" class="wp-caption aligncenter" style="width: 370px"><a href="http://wordpress.holographer.net/wp-content/uploads/2004/04/hgr0011.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2004/04/hgr0011.jpg" alt="a. The diagram of a microscope slide coated with a smart polymer layer, which has been impregnated with photosensitive silver bromide, being exposed  in  a  trough  of  aqueous  liquid.  b. An  actual  transmission  electron micrograph  showing  the  very  fine  grain  size  achieved  to  make  the  fringe structure." title="a. The diagram of a microscope slide coated with a smart polymer layer, which has been impregnated with photosensitive silver bromide, being exposed  in  a  trough  of  aqueous  liquid.  b. An  actual  transmission  electron micrograph  showing  the  very  fine  grain  size  achieved  to  make  the  fringe structure." width="360" height="460" class="size-full wp-image-475" /></a><p class="wp-caption-text">a. The diagram of a microscope slide coated with a smart polymer layer, which has been impregnated with photosensitive silver bromide, being exposed  in  a  trough  of  aqueous  liquid.  b. An  actual  transmission  electron micrograph  showing  the  very  fine  grain  size  achieved  to  make  the  fringe structure.</p></div></p>
<p>So the success had come by sequentially diffusing into the layer, a solution of silver nitrate and following it up by diffusing in a solution of lithium bromide. (I chose lithium rather than the common potassium salt because I thought I might need the extra leeway of its very large solubility in both water and alcohol&nbsp;<span class="cite">[<a  href="#X3">3</a>]</span>.) </p>
<p>The reason this was such a breakthrough was that we could then use the principle on a whole range of pre-coated hydrophilic polymers which responded to various specific factors in the environment.
<p> The vast majority of tests required in biotechnology are made in physiologically based aqueous liquids, so polymers need to be hydrophilic from this standpoint apart from the fact that the precipitation of AgBr is an ion exchange process which does not lend itself to taking place in a hydrophobic polymer. So an early question was just to see how far the scope of this diffusion process could be taken towards the hydrophobic end between the typical extremes of say polyacrylamide and polypropylene. Using as reactants the two most soluble salts of silver and bromine in organic liquids, namely silver perchlorate and lithium bromide, I tested out the sequential diffusion system on a few different polymers that were to hand. I found I could get reflection holograms in the cellulose based wrappers commonly on so many of our consumer products. But I did not manage to get any result on the backside of a piece of old Agfa holographic film. This meant that cellulose triacetate was too hydrophobic but with the help of a proportion of acetone I did manage to get an &#x2018;OK&#x2019; result in cellulose diacetate polymer film. </p>
<p>I also managed to get a hologram in nylon (polyamide) but it was not brilliant. I must say at once for those who instantly jump as I did, to the idea of putting holographic gratings <b>inside</b> the fabric of say nylon tights, I had used nylon film and&nbsp;not&nbsp;mesh. I did, however, carry out a few experiments trying it with nylon mesh where the first requirement was to &#x201C;index out&#x201D; the mesh i.e.&nbsp;make it invisible by a suitable liquid to actually record the hologram. Although I managed to make the pure mesh almost disappear in an organic liquid (DMSO), the act of putting the AgBr salt inside the nylon mesh caused some unavoidable refractive index variation and therefore bad light scatter so I only got <i>photographic</i> images in silver, not <i>holographic</i>. A pulsed 532&nbsp;nm YAG laser was used so movement did not cause the failure.
<p> As for other common plastics, I found &#x201C;Perspex&#x201D; or PMMA (polymethylmethacrylate) to be too hydrophobic whereas poly(hydroxy)methylmethacrylate or poly-HEMA is excellent at forming bright holograms. A nice piece of work carried out in 1998 by my colleague Andrew Mayes (now at the University of East Anglia) used a small polyHEMA hologram to make very effective measurements of the alcohol content of various drinks&nbsp;<span class="cite">[<a  href="#X4">4</a>]</span>. I show the table of his results in <a  href="#x1-10031">table&nbsp;1<!--tex4ht:ref: tab01 --></a>. Strong spirits are not included in the table because they shift the hologram replay wavelength into the infrared&#x2014;beyond the range of the small reflection spectrometer available for us at the&nbsp;time. </p>
<p><a name="x1-10022"></a><div id="attachment_480" class="wp-caption aligncenter" style="width: 322px"><a href="http://wordpress.holographer.net/wp-content/uploads/2004/04/hgr0021.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2004/04/hgr0021.jpg" alt="The slide is sliced up and placed in a sample liquid in a cuvette. As the substance in the liquid alters then the replay colour of the hologram may change. In the 3 cuvettes shown, the same polymer material is contracting from left to right." title="The slide is sliced up and placed in a sample liquid in a cuvette. As the substance in the liquid alters then the replay colour of the hologram may change. In the 3 cuvettes shown, the same polymer material is contracting from left to right." width="312" height="283" class="size-full wp-image-480" /></a><p class="wp-caption-text">The slide is sliced up and placed in a sample liquid in a cuvette. As the substance in the liquid alters then the replay colour of the hologram may change. In the 3 cuvettes shown, the same polymer material is contracting from left to right.</p></div></p>
<table class="float" style="border-top: 1px dotted #6464dc; border-bottom: 1px dotted #6464dc; padding-top: 2px; padding-bottom: 2px; ">
<tr class="float">
<td class="float" ><strong>Table&nbsp;1.</strong>&nbsp;Stated alcohol content of 17 drinks compared with the alcohol content measured with the holographic sensor, together with the pH and conductivity data for each drink<a    id="x1-10031"></a></p>
<table class="tabular" width="100%"  cellspacing="2" cellpadding="5" frame="void" id="TBL-1-">
<colgroup id="TBL-1-1g">
<col  id="TBL-1-1" />
<col  id="TBL-1-2" />
<col  id="TBL-1-3" />
<col  id="TBL-1-4" />
<col  id="TBL-1-5" />
<col  id="TBL-1-6" />
<col  id="TBL-1-7" /></colgroup>
<tr   bgcolor="#ecec9c" valign="baseline" id="TBL-1-1-">
<td  align="left" valign="middle" bgcolor="#ecec9c"   class="td11" id="TBL-1-1-1" style="white-space:nowrap;"> </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-1-2"   class="td11">             </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-1-3"   class="td11">         </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-1-4"   class="td11">                   </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-1-5"   class="td11">                  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-1-6"   class="td11">  Calc      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-1-7"   class="td11">             </td>
</tr>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-1-2-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-2-1"   class="td11">                                             </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-2-2"   class="td11">  Alcohol  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-2-3"   class="td11">         </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-2-4"   class="td11">  Conductivity  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-2-5"   class="td11">  Wavelength  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-2-6"   class="td11">  alcohol  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-2-7"   class="td11">  Error     </td>
</tr>
<tr    bgcolor="#ecec9c"   valign="baseline" id="TBL-1-3-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-3-1"   class="td11">  Beverage                               </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-3-2"   class="td11">  (vol %)  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-3-3"   class="td11">  pH   </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-3-4"   class="td11">  (mS/cm)      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-3-5"   class="td11">  (nm)          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-3-6"   class="td11">  (vol %)  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-3-7"   class="td11">  (vol %)  </td>
</tr>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-1-4-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-4-1"   class="td11">  Kaliber lager (Guiness)               </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-4-2"   class="td11">   0.03    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-4-3"   class="td11">  4.10  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-4-4"   class="td11">  0.91            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-4-5"   class="td11">  503.6          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-4-6"   class="td11">  &#x2212;0.32    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-4-7"   class="td11">  &#x2212;0.35    </td>
</tr>
<tr    bgcolor="#ecec9c"   valign="baseline" id="TBL-1-5-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-5-1"   class="td11">  Swan Light lager                     </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-5-2"   class="td11">   1        </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-5-3"   class="td11">  3.70  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-5-4"   class="td11">  0.84            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-5-5"   class="td11">  514.2          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-5-6"   class="td11">    1.21    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-5-7"   class="td11">    0.21    </td>
</tr>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-1-6-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-6-1"   class="td11">  Steinbrau lager                         </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-6-2"   class="td11">   3        </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-6-3"   class="td11">  3.95  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-6-4"   class="td11">  0.79            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-6-5"   class="td11">  524.9          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-6-6"   class="td11">    2.67    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-6-7"   class="td11">  &#x2212;0.33    </td>
</tr>
<tr    bgcolor="#ecec9c"   valign="baseline" id="TBL-1-7-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-7-1"   class="td11">  Heiniken lager                         </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-7-2"   class="td11">   5        </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-7-3"   class="td11">  4.26  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-7-4"   class="td11">  1.16            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-7-5"   class="td11">  542.3          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-7-6"   class="td11">    4.88    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-7-7"   class="td11">  &#x2212;0.12    </td>
</tr>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-1-8-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-8-1"   class="td11">  Carlsberg Special Brew               </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-8-2"   class="td11">   9        </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-8-3"   class="td11">  4.11  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-8-4"   class="td11">  0.96            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-8-5"   class="td11">  575.6          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-8-6"   class="td11">    8.72    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-8-7"   class="td11">  &#x2212;0.28    </td>
</tr>
<tr    bgcolor="#ecec9c"   valign="baseline" id="TBL-1-9-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-9-1"   class="td11">  Weihenstephaner Hefe Weissbier  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-9-2"   class="td11">   5.4      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-9-3"   class="td11">  4.31  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-9-4"   class="td11">  1.05            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-9-5"   class="td11">  547.1          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-9-6"   class="td11">    5.47    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-9-7"   class="td11">    0.07    </td>
</tr>
<tr    bgcolor="#cecece"  valign="baseline" id="TBL-1-10-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-10-1"   class="td11">  Woodpecker cider (Bulmers)       </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-10-2"   class="td11">   3.5      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-10-3"   class="td11">  3.19  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-10-4"   class="td11">  0.76            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-10-5"   class="td11">  534.4          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-10-6"   class="td11">    3.90    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-10-7"   class="td11">    0.40    </td>
</tr>
<tr   bgcolor="#ecec9c" valign="baseline" id="TBL-1-11-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-11-1"   class="td11"> &#x201C;Katy&#x201D; strong cider (Thatchers)  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-11-2"   class="td11">   7.4      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-11-3"   class="td11">  3.46  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-11-4"   class="td11">  0.91            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-11-5"   class="td11">  563.6          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-11-6"   class="td11">    7.39    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-11-7"   class="td11">  &#x2212;0.01    </td>
</tr>
<tr   bgcolor="#cecece" valign="baseline" id="TBL-1-12-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-12-1"   class="td11"> White Label Bitter (Whitbread)    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-12-2"   class="td11">   1        </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-12-3"   class="td11">  4.01  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-12-4"   class="td11">  0.66            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-12-5"   class="td11">  513.5          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-12-6"   class="td11">    1.11    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-12-7"   class="td11">    0.11    </td>
</tr>
<tr   bgcolor="#ecec9c" valign="baseline" id="TBL-1-13-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-13-1"   class="td11"> Exmoor Gold Bitter                  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-13-2"   class="td11">   5        </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-13-3"   class="td11">  4.07  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-13-4"   class="td11">  1.17            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-13-5"   class="td11">  543.4          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-13-6"   class="td11">    5.02    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-13-7"   class="td11">    0.02    </td>
</tr>
<tr   bgcolor="#cecece" valign="baseline" id="TBL-1-14-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-14-1"   class="td11"> Newcastle Brown Ale                 </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-14-2"   class="td11">   4.7      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-14-3"   class="td11">  3.88  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-14-4"   class="td11">  0.87            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-14-5"   class="td11">  541.3          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-14-6"   class="td11">    4.76    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-14-7"   class="td11">    0.06    </td>
</tr>
<tr   bgcolor="#ecec9c" valign="baseline" id="TBL-1-15-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-15-1"   class="td11"> Guiness                                 </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-15-2"   class="td11">   4.3      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-15-3"   class="td11">  3.91  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-15-4"   class="td11">  0.99            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-15-5"   class="td11">  539.2          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-15-6"   class="td11">    4.50    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-15-7"   class="td11">    0.20    </td>
</tr>
<tr   bgcolor="#cecece" valign="baseline" id="TBL-1-16-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-16-1"   class="td11"> Hoopers Hooch                        </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-16-2"   class="td11">   4.7      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-16-3"   class="td11">  2.77  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-16-4"   class="td11">  0.81            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-16-5"   class="td11">  536.5          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-16-6"   class="td11">    4.16    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-16-7"   class="td11">  &#x2212;0.54    </td>
</tr>
<tr   bgcolor="#ecec9c" valign="baseline" id="TBL-1-17-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-17-1"   class="td11"> Liebfraumilch white wine           </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-17-2"   class="td11">   9.5      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-17-3"   class="td11">  3.36  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-17-4"   class="td11">  1.00            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-17-5"   class="td11">  582.4          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-17-6"   class="td11">    9.45    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-17-7"   class="td11">  &#x2212;0.05    </td>
</tr>
<tr   bgcolor="#cecece" valign="baseline" id="TBL-1-18-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-18-1"   class="td11"> French red wine                       </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-18-2"   class="td11">  11.5      </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-18-3"   class="td11">  3.56  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-18-4"   class="td11">  1.40            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-18-5"   class="td11">  600.9          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-18-6"   class="td11">    11.36  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-18-7"   class="td11">  &#x2212;0.14    </td>
</tr>
<tr   bgcolor="#ecec9c" valign="baseline" id="TBL-1-19-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-19-1"   class="td11"> French white wine                    </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-19-2"   class="td11">  11        </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-19-3"   class="td11">  3.29  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-19-4"   class="td11">  0.97            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-19-5"   class="td11">  603.3          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-19-6"   class="td11">    11.60  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-19-7"   class="td11">    0.60    </td>
</tr>
<tr   bgcolor="#cecece" valign="baseline" id="TBL-1-20-">
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-20-1"   class="td11"> Ruby port                               </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-20-2"   class="td11">  20        </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-20-3"   class="td11">  3.55  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-20-4"   class="td11">  0.69            </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-20-5"   class="td11">  683.2          </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-20-6"   class="td11">    18.85  </td>
<td valign="middle"  align="left" style="white-space:nowrap;" id="TBL-1-20-7"   class="td11">  &#x2212;1.15    </td>
</tr>
</table>
</td>
</tr>
</table>
<p>I remember we had a bit of trouble reclaiming the petty cash from the accounts department for this lot and had to convince them that it really was for a new scientific breakthrough. (Actually we only needed about 5&nbsp;ml out of each bottle and as for the rest of each bottle&#8230; Well, we did not want to bother them with the finer details of the experiment!) </p>
<p>For several years we have been making polymers with certain chemical groups able to respond specifically to specific ions, enzymes and other analytes by swelling or contracting in saline solution, so when we make a reflection hologram of a mirror in these &#x201C;smart&#x201D; polymers we obtain a &#x201C;smart hologram&#x201D;mirror. (see: the OE magazine report &#x2013; <a href="http://www.oemagazine.com/fromTheMagazine/mar03/diagnostics.html" target="_blank">http://www.oemagazine.com/fromTheMagazine/mar03/diagnostics.html</a>)
<p> In a future article in the Holographer I hope to reveal more about the amazing possibilities opened up by this new holographic ball game. </p>
<p class="section-head">References</p>
<p class="bibitem"><span class="biblabel">   [1]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X1"></a>         J.&nbsp;&nbsp;Blyth <i>et al.</i>&nbsp;1996 <i>Anal. Chem.</i> 68 1089&#x2013;94     </p>
<p class="bibitem"><span class="biblabel">   [2]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X2"></a>         H.&nbsp;&nbsp;Thiry&nbsp;1987 <i>J. Phot. Sci.</i> 35 150&#x2013;4     </p>
<p class="bibitem"><span class="biblabel">   [3]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X3"></a>         J.&nbsp;&nbsp;Blyth <i>et al.</i>&nbsp;1999 <i>Imaging Sci. J.</i> 47 87&#x2013;91     </p>
<p class="bibitem"><span class="biblabel">   [4]<span class="bibsp">&nbsp;&nbsp;&nbsp;</span></span><a    id="X4"></a>         A.&nbsp;&nbsp;Mayes <i>et al.</i>&nbsp;1999 <i>Anal. Chem.</i> 71 3390&#x2013;6 </p>
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		<title>HoloGraphics: combining holograms with interactive computer graphics</title>
		<link>http://holographer.org/holographics-combining-holograms-with-interactive-computer-graphics/</link>
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		<pubDate>Tue, 23 Mar 2004 07:47:45 +0000</pubDate>
		<dc:creator>Kaveh</dc:creator>
				<category><![CDATA[Technique]]></category>
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		<category><![CDATA[Computer graphics]]></category>
		<category><![CDATA[Holograms]]></category>
		<category><![CDATA[HoloGraphics]]></category>
		<category><![CDATA[Oliver Bimber]]></category>

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Oliver Bimberbimber@ieee.org
About the author Oliver Bimber is a Junior Professor for Augmented Reality at the Bauhaus University Weimar in Germany. He holds a PhD in Computer Science from Technical University of Darmstadt. Contact him at bimber@ieee.org. More information is available at http://www.HoloGraphics.de


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Just like computer graphics, holograms are being applied as tools to solve individual [...]]]></description>
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<p><img src="http://wordpress.holographer.net/wp-content/uploads/2009/06/bimber-photo.jpg" alt="bimber-photo" title="bimber-photo" width="100" height="129" style="border: 1px solid #ddd;" class="alignleft size-full wp-image-326" /><span class="author">Oliver Bimber</span><br /><span><a href="mailto:bimber@ieee.org" target="_blank">bimber@ieee.org</a></span></p>
<p class="bio"><strong>About the author</strong><br /> Oliver Bimber is a Junior Professor for Augmented Reality at the Bauhaus University Weimar in Germany. He holds a PhD in Computer Science from Technical University of Darmstadt. Contact him at <a href="mailto:bimber@ieee.org" target="_blank">bimber@ieee.org</a>. More information is available at <a href="http://www.HoloGraphics.de" target="_blank">http://www.HoloGraphics.de</a></p>
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<p>Just like computer graphics, holograms are being applied as tools to solve individual research, engineering, and presentation problems within several domains. Up until today, however, these tools have been applied separately. The overall goal of our project is to combine both technologies to create a powerful tool for science, industry and education. We are currently investigating the possibility of integrating computer generated graphics and holograms.</p>
<p>Our goal is to combine the advantages of conventional holograms (i.e. extremely high visual quality and realism, support for all depth queues and for multiple observers at no computational cost, space efficiency, etc.) with the advantages of today’s computer graphics capabilities (i.e. interactivity, real-time rendering, simulation and animation, stereoscopic and autostereoscopic presentation, etc.). </p>
<p>Several engineering and computer science topics will be addressed throughout the project: The potentials of different hologram types with respect to the project’s goal have to be investigated. New three-dimensional displays that combine computer graphics and holography will be engineered. New real-time rendering algorithms, registration methods, and human–computer interaction techniques that are adequate for the proposed metaphor will be developed. </p>
<p> The outcome will be a three-dimensional display concept whose application is envisioned in areas such as scientific visualization (e.g., paleontology, pathology, density, medicine, biomedicine, orthopedics or archeology), industrial simulation (e.g., design, manufacturing and quality assurance), and education (e.g., medical training or public museums).</p>
<p>Here are some of our initial results. </p>
<p class="section-head">Using digital light to reconstruct the holographic image</p>
<p>The two basic hologram types—transmission and reflection—are both reconstructed by illuminating them with spatially coherent light (i.e. using a point-source of light). These two types have generated a number of variations. Although some holograms can be reconstructed only with laser light, others can be viewed under white light.</p>
<p>Rainbow holograms, one of the most popular types of white-light transmission hologram, diffract each wavelength of the light through a different angle. This lets viewers observe the recorded scene from different horizontal viewing positions but also makes the scene appear in different colors when observed from different vertical points of view. In contrast to rainbow holograms, white-light reflection holograms can provide full parallax and display the recorded scene in a consistent color (monochrome or multi-color) for different viewing positions. </p>
<p> Conventional video projectors represent point sources that are well suited for viewing white-light reflection or transmission holograms. Today’s high-intensity discharge lamps of projectors can produce a very bright light. The main advantage for using video projectors is that the reference wave used to reconstruct the hologram can be digitized. Thus it is possible to control the amplitude and wavelength of each discrete portion of the wavefront over time. </p>
<p><a name="x1-20011"></a><div id="attachment_338" class="wp-caption aligncenter" style="width: 510px"><a href="/media/articles/images/hg00011/hgr001.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2004/08/hgr001-500px.jpg" alt="Figure 1: The projected reference waves and the resulting holographic images." title="The projected reference waves and the resulting holographic images" width="500" height="270" class="size-full wp-image-338" /></a><p class="wp-caption-text">Figure 1: The projected reference waves and the resulting holographic images.</p></div></p>
<p><a href="#x1-20011">Figure 1</a> shows the projected reference wave in different states, and the resulting holographic image of a monochrome white-light reflection hologram. A uniform reference wave reconstructs the entire hologram uniformly. Selectively emitting light in different directions allows us to create an incomplete reference wave that reconstructs the hologram only partially. Local amplitude variations in the reference wave result in proportional amplitude variations in the reconstructed object wave. Variations in wavelength do not lead to useful effects in most cases due to the wavelength dependency of holograms. But this is still a matter for further investigations.</p>
<p class="section-head">Partially reconstructing object waves</p>
<p> It is possible to reconstruct the object wave of a hologram only partially, leaving gaps where graphical elements can be inserted. </p>
<p>Both reflection holograms (without an opaque backing layer) and transmission holograms remain transparent if not illuminated. Thus, they can serve as optical combiners—leading to very compact displays.</p>
<p>Real-time computer graphics can be integrated into the hologram from one side, while illuminating it partially from the other side [<a href="#Xbib1">1</a>]. Thereby, rendering and illumination are view-dependent and have to be synchronized.</p>
<p>
If autostereoscopic displays are used to render 3D graphics registered to the hologram, both holographic and graphical content appear three-dimensional within the same space. If depth information of both is known, correct occlusion effects between hologram and graphics can be generated.
</p>
<p><a name="x1-30012"></a><div id="attachment_341" class="wp-caption aligncenter" style="width: 510px"><a href="/media/articles/images/hg00011/hgr002.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2004/08/hgr002-500px.jpg" alt="Figure 2: Rainbow  hologram  of  a  dinosaur  skull  combined  with  graphical representations of soft tissue and bones." title="Rainbow  hologram  of  a  dinosaur  skull  combined  with  graphical representations of soft tissue and bones." width="500" height="188" class="size-full wp-image-341" /></a><p class="wp-caption-text">Figure 2: Rainbow  hologram  of  a  dinosaur  skull  combined  with  graphical representations of soft tissue and bones.</p></div></p>
<p><a href="#x1-30012">Figure&nbsp;2</a> shows a rainbow hologram of a dinosaur skull combined with graphical representations of soft tissue and bones. If the holographic plate is illuminated with a uniform light, the entire hologram is reconstructed. If the plate is illuminated only at the portions not occluded by graphical elements, the synthetic objects can be integrated by displaying them on the screen behind the plate. </p>
<p class="section-head">Light interaction</p>
<p>The reconstructed object wave&#x2019;s amplitude is proportional to the reference wave&#x2019;s intensity. In addition to using an incomplete reference wave for reconstructing a fraction of the hologram, intensity variations of the projected light permit local modification of the recorded object wave&#x2019;s amplitude.</p>
<p>Practically, this means that to create the illumination image which is sent out by the projector, graphical shading and shadowing techniques are used to reconstruct the hologram instead of illuminating it with a uniform intensity. To do this, the real shading effects on the captured scenery caused by the real light sources used for illumination during hologram recording, as well as the physical lighting effects caused by the video projector on the holographic plate, must both be neutralized. Next, the influence of a synthetic illumination must be simulated&nbsp;[<a href="#Xbib1">1</a>].</p>
<p>Using conventional graphics hardware, it becomes possible not only to create consistent shading effects, but also to cast synthetic shadows correctly from all holographic and graphical elements onto all other elements.</p>
<p><a name="x1-40013"></a><div id="attachment_342" class="wp-caption aligncenter" style="width: 510px"><a href="/media/articles/images/hg00011/hgr003.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2004/08/hgr003-500px.jpg" alt="Figure 3: A  rainbow  hologram  with  3D  graphical  elements  and  synthetic shading and shadow effects." title="A  rainbow  hologram  with  3D  graphical  elements  and  synthetic shading and shadow effects." width="500" height="188" class="size-full wp-image-342" /></a><p class="wp-caption-text">Figure 3: A  rainbow  hologram  with  3D  graphical  elements  and  synthetic shading and shadow effects.</p></div></p>
<p>The figures show the same rainbow hologram as above with 3D graphical elements and synthetic shading effects. Shadows are cast correctly from the hologram onto the graphics and vice versa. A virtual point-source of light was first located at the top-left corner, and then moved to the top-right corner, in front of the display.</p>
<p class="section-head">Proof-of-concept prototypes</p>
<p>The desktop prototypes shown in <a href="#x1-50014">figure&nbsp;4</a> consist entirely of off-the-shelf components, including either an autostereoscopic lenticular-lens sheet display with an integrated head-finder for wireless user tracking, or a conventional CRT screen with active stereo glasses, wireless infrared tracking, and a touch screen for interaction.</p>
<p>Both prototypes use digital light projectors. A single PC with a dual-output graphics card renders the graphical content on the screen and illuminates the holographic plate on the video projector.</p>
<p><a name="x1-50014"></a><div id="attachment_344" class="wp-caption aligncenter" style="width: 473px"><a href="/media/articles/images/hg00011/hgr004.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2004/08/hgr004-500px.jpg" alt="Figure 4: An autostereoscopic (left) and a stereoscopic (right) proof-of-concept prototype." title="An autostereoscopic (left) and a stereoscopic (right) proof-of-concept prototype." width="463" height="221" class="size-full wp-image-344" /></a><p class="wp-caption-text">Figure 4: An autostereoscopic (left) and a stereoscopic (right) proof-of-concept prototype.</p></div></p>
<p>In both cases, the screen additionally holds further front layers&#x2014;glass protection, holographic emulsion, and optional mirror beam splitter (used for transmission holograms only).</p>
<p>Interaction with the graphical content is supported with a mouse or a transparent touch-screen mounted in front of the holographic plate.</p>
<p class="section-head">Experiments with a digital multiplex hologram</p>
<p>Digital holography uses holographic printers to expose the photosensitive emulsion with computer generated or captured images.</p>
<p>This results in conventional holograms with digital content rather than real scenery. Pre-processed 2D and 3D graphics or digital photographs and movies can be printed. This allows, for instance, the holographic recording of completely synthetic objects, real outdoor scenes, and objects in motion&#x2014;which is difficult and sometimes impossible to achieve with optical holography.
</p>
<p>Like optical holograms, digital holograms can be multiplexed. This allows us to divide the viewing space and to assign individual portions to different contents.
<p>The content for digital holograms can easily be created by non-experts, and the printing process is inexpensive. Usually a 3D graphical scene, a series of digital photographs or a short movie of a real object is sufficient for producing digital holograms. However, these digital holograms lack in the quality (resolution, color appearance, sharpness, etc.) of conventional optical holograms.</p>
<p><a name="x1-60015"></a><div id="attachment_345" class="wp-caption aligncenter" style="width: 510px"><a href="/media/articles/images/hg00011/hgr005.jpg"><img src="http://wordpress.holographer.net/wp-content/uploads/2004/08/hgr005-500px.jpg" alt="Figure 5: A multiplexed digital reflection hologram of a car headlight with integrated CAD data." title="A multiplexed digital reflection hologram of a car headlight with integrated CAD data." width="500" height="302" class="size-full wp-image-345" /></a><p class="wp-caption-text">Figure 5: A multiplexed digital reflection hologram of a car headlight with integrated CAD data.</p></div></p>
<p><a href="#x1-60015">Figure&nbsp;5</a> shows a digital color white-light reflection hologram of a car headlight. It was generated by taking 360 perspective photographs from different angles (in 0.5<sup >&#x2218;</sup> steps to cover a 110<sup >&#x2218;</sup> total viewing zone plus two 35<sup>&#x2218;</sup> clipping areas). The perspective photographs were multiplexed into different sub-zones (40<sup >&#x2218;</sup> = 80&nbsp;images for the front view +&nbsp;2 &#x00D7; 35<sup >&#x2218;</sup> = 140 images for the side and rear views + &nbsp;2 &#x00D7; 12.5<sup >&#x2218;</sup> = 50 images to fill the partially visible clipping area outside the 110<sup >&#x2218;</sup> total viewing zone +&nbsp;2 &#x00D7; 22.5<sup >&#x2218;</sup> = 90 images to fill the invisible clipping area outside the 110<sup >&#x2218;</sup> total viewing zone).</p>
<p>Consequently, three different partial views (front, rear, and side) can be observed by moving within the total viewing zone of 110<sup >&#x2218;</sup>. After registering the holographic plane and calibrating the projector, interactive graphical elements, such as wire-frame or shaded CAD data can be integrated into the hologram.</p>
<p class="section-head">Holographic windows</p>
<p>The ability to control the reconstruction of a hologram&#x2019;s object wave allows integrating them seamlessly into common desktop-window environments.</p>
<p>If the holographic emulsion that is mounted in front of a screen is not illuminated, it remains transparent. In this case the entire screen content is visible and an interaction with software applications on the desktop is possible in a familiar way.</p>
<p>The holographic content (visible or not) is always located at a fixed spatial position within the screen/desktop reference frame. An application that renders the graphical content does not necessarily need to be displayed in full-screen mode (as in the examples above), but can run in a &#x2018;windows&#x2019; mode&#x2014;covering an arbitrary area on the desktop behind the emulsion.</p>
<p>If the position and the dimensions of the graphics window are known, the projector-based illumination can be synchronized to bind the reference wave to the portion of the emulsion that is located directly on top of the underlying window. Thereby, all the techniques that are described above (partial reconstruction and intensity variations) are constrained to the window&#x2019;s boundaries. The remaining portion of the desktop is not influenced by the illumination, the graphical or the holographic content.</p>
<p>In addition, the graphical content can be rendered in such a way that it remains registered with the holographic content&#x2014;even if the graphical window is moved or resized.</p>
<p>This simple, but effective technique allows a seamless integration of holograms into common desktop environments. It allows us to temporarily minimize the &#x201C;holographic window&#x201D; or to align it over the main focus while working other applications.</p>
<p><a name="x1-70016"></a><div id="attachment_349" class="wp-caption aligncenter" style="width: 510px"><a href="/media/articles/images/hg00011/hgr006.jpg" target="_blank"><img src="http://wordpress.holographer.net/wp-content/uploads/2004/08/hgr006-500px.jpg" alt="Figure 6: A holographic window in different states on a desktop together with other applications." title="A holographic window in different states on a desktop together with other applications." width="500" height="126" class="size-full wp-image-349" /></a><p class="wp-caption-text">Figure 6: A holographic window in different states on a desktop together with other applications.</p></div></p>
<p><a href="#x1-70016">Figure&nbsp;6</a> shows a holographic window in different states on a desktop together with other applications. It displays an optical (monochrome) white-light reflection hologram of a dinosaur skull with integrated graphical 3D soft tissues. A stereoscopic screen was used in this case, because autostereoscopic displays (such as lenticular screens or barrier displays) do not yet allow an undisturbed view on a non-interlaced 2D content.</p>
<p class="section-head">Outlook</p>
<p>Holograms can store a massive amount of information on a thin holographic emulsion. This technology can record and reconstruct a 3D scene with almost no loss in quality. Moore&#x2019;s law&#x2014;which asserts that computing power doubles every 18 months&#x2014;must be applied many times for graphical or electro-holographic rendering techniques and displays in order to reach this quality at interactive frame rates. A combination of interactive computer graphics and high-quality holograms represents an alternative that can be realized today with off-the-shelf consumer hardware. We believe that this concept can be beneficial for many applications.</p>
<p>Archaeologists, for example, already use holograms to archive and investigate ancient artifacts. Scientists can use hologram copies to perform their research without having access to the original artifacts or settling for inaccurate replicas. They can combine these holograms with interactive computer graphics to integrate real-time simulation data or perform experiments that require direct user interaction, such as packing reconstructed soft tissue into a fossilized dinosaur skull hologram. In addition, specialized interaction devices can simulate haptic feedback of holographic and graphical content while scientists are performing these interactive tasks. An entire collection of artifacts will fit into a single album of holographic recordings, while a light-box-like display such as that used for viewing x-rays can be used for visualization and interaction.</p>
<p>The same applies to the biomedical domain that already uses digital volumetric holograms produced from CT or MRI data of inner organs.</p>
<p>In the automotive industry, for instance, complex computer models of cars and components often lack realism or interactivity. Instead of attempting to achieve high visual quality and interactive frame rates for the entire model, designers could decompose the model into sets of interactive and static elements. The system could record physical counterparts of static elements in a hologram with maximum realism, and release computational resources to render the interactive elements with a higher quality and increased frame rate. Multiplexing the holographic content also lets users observe and interact with the entire model from multiple perspectives. Beside display holograms, holographic interferograms used for non-destructive measurement and testing are yet another example of industrial applications. Analogue interferograms that indicate motion, vibration, or deformations of objects can be combined with digital simulation data.</p>
<p>Augmenting holograms in museums with animated multimedia content lets exhibitors communicate information about the artifact with more excitement and effectiveness than text labels offer. Such displays can also respond to user interaction. Because wall-mounted variations require little space, museums can display a larger number of artifacts.</p>
<p><a name="x1-80017"></a><div id="attachment_351" class="wp-caption aligncenter" style="width: 449px"><a href="/media/articles/images/hg00011/hgr007.jpg"><img src="http://wordpress.holographer.net/wp-content/uploads/2004/08/hgr007-500px.jpg" alt="Figure 7: Illustrations of envisioned future applications: Museum displays, and scientific visualization and simulation." title="Illustrations of envisioned future applications: Museum displays, and scientific visualization and simulation." width="439" height="242" class="size-full wp-image-351" /></a><p class="wp-caption-text">Figure 7: Illustrations of envisioned future applications: Museum displays, and scientific visualization and simulation.</p></div></p>
<p><a href="#x1-80017">Figure&nbsp;7</a> shows two illustrations of envisioned future applications: A wall-mounted display in a museum environment, with a ceiling-mounted video projector replacing conventional spotlights, and a desktop display that can be used in a light-box fashion. A special input device allowing interaction, including haptic feedback of holographic and graphical content.</p>
<p>The technical and scientific progress that is planned to be made during this project can be organized into six linked goals:</p>
<dl>
<dt>Holograms</dt>
<dd>Investigation of different hologram types and individual solutions that combine them with computer graphics. Optimization of optical properties during the recording process to achieve the best possible effects.</dd>
<dt>Displays</dt>
<dd>Experiments with different optical setups that support the integration of computer graphics into the different hologram types. Experiments with different stereoscopic and autostereoscopic techniques. Investigation of different display form factors that serve a variety of applications.</dd>
<dt>Calibration and registration</dt>
<dd>Development of fully- or semi-automated methods that calibrate the display optics, extract auxiliary information (such as depth) recorded in the hologram and register holographic and graphical content.</dd>
<dt>Rendering</dt>
<dd>Development of effective rendering and illumination algorithms that support different hologram types, special effects, and a realistic and consistent presentation of holographic and graphical content at interactive frame rates.</dd>
<dt>Interaction</dt>
<dd>Investigation of the potentials and limitations of existing interaction techniques and devices in combination with interactive holograms. Development of new interaction forms that are suited for the different display approaches and potential application areas.</dd>
<dt>Demonstration and evaluation</dt>
<dd>Implementation of demonstrators that address different application areas. The effectiveness of the proposed concept is evaluated by presenting the demonstrators to domain experts.</dd>
</dl>
<p class="section-head">Acknowledgements</p>
<p>This project is supported by the Deutsche Forschungsgemeinschaft (DFG). The experiments shown in figure 5 were supported by DaimlerChrysler AG Research Technology. The content shown in <a href="#x1-30012">figures&nbsp;2</a>, <a href="#x1-40013">3</a> and <a href="#x1-70016">6</a> was provided by Ohio University&#x2019;s department of Biomedical Sciences. The HoloGraphics project is supported by the Deutsche Forschungsgemeinschaft (DFG).</p>
<p class="section-head">References</p>
<p class="bibitem"><span class="biblabel">[1]<span class="bibsp">&nbsp;</span></span><a name="Xbib1"></a> <strong>O.&nbsp;Bimber</strong>&nbsp;January 2004 Combining holograms with interactive computer graphics IEEE Computer 85&#x2013;91</p>
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